Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/101009

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題名:	Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands
作者:	Lin, Wan-Jung;Abbas Raja Naziruddin;Chen, Yu-Hsuan;Sun, Bian-Jian;Chang, Hsiu Hwa;Wang, Wen-Jwu;Hwang, Wen-Shu
貢獻者:	淡江大學化學學系
關鍵詞:	N-heterocyclic carbene complexes;photoactive platinum complexes;stimuli-responsive emission
日期:	2015-03-01
上傳時間:	2015-03-19 15:08:01 (UTC+8)
出版者:	Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA
摘要:	Photoactive platinum complexes of stoichiometry [Pt(RCCCR)L]0/+ (R=Me, nBu and L=[BOND]CN, [BOND]C≡CPh, [BOND]N≡CCH3, [BOND]Py, [BOND]CO) featuring pincer-type bis N-heterocyclic carbene (NHC) ligands (RCCCR) were synthesized. Organometallic syntheses of these complexes are facile and achievable through standard laboratory procedures. Control of intermolecular Pt⋅⋅⋅Pt interaction, π–π stacking, and emission tuning is achieved through suitable choice of the NHC-wingtip substituent (R) and the auxiliary ligand (L). Exposure to specific volatile organic compounds (VOCs) or mechanical grinding triggers changes in emission colors, which render these complexes photofunctional. Solid-state structures and photoluminescence results are described herein.
關聯:	Chemistry – An Asian Journal 10(3), pp.728-739
DOI:	10.1002/asia.201403306
顯示於類別:	[化學學系暨研究所] 期刊論文

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