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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/101009

    Title: Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands
    Authors: Lin, Wan-Jung;Abbas Raja Naziruddin;Chen, Yu-Hsuan;Sun, Bian-Jian;Chang, Hsiu Hwa;Wang, Wen-Jwu;Hwang, Wen-Shu
    Contributors: 淡江大學化學學系
    Keywords: N-heterocyclic carbene complexes;photoactive platinum complexes;stimuli-responsive emission
    Date: 2015-03-01
    Issue Date: 2015-03-19 15:08:01 (UTC+8)
    Publisher: Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA
    Abstract: Photoactive platinum complexes of stoichiometry [Pt(RCCCR)L]0/+ (R=Me, nBu and L=[BOND]CN, [BOND]C≡CPh, [BOND]N≡CCH3, [BOND]Py, [BOND]CO) featuring pincer-type bis N-heterocyclic carbene (NHC) ligands (RCCCR) were synthesized. Organometallic syntheses of these complexes are facile and achievable through standard laboratory procedures. Control of intermolecular Pt⋅⋅⋅Pt interaction, π–π stacking, and emission tuning is achieved through suitable choice of the NHC-wingtip substituent (R) and the auxiliary ligand (L). Exposure to specific volatile organic compounds (VOCs) or mechanical grinding triggers changes in emission colors, which render these complexes photofunctional. Solid-state structures and photoluminescence results are described herein.
    Relation: Chemistry – An Asian Journal 10(3), pp.728-739
    DOI: 10.1002/asia.201403306
    Appears in Collections:[化學學系暨研究所] 期刊論文

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