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    Title: Cubic Phase Formation from New Hexacatenar Metallomesogens Based on Cobalt 3,4,5-Trialkoxybenzoate
    Authors: Lin, Chien-Ho;Kao, Hsien-Chang;Sung, Wen-Te;Cheng, Yao-Wen;Wang, Wen-Jwu
    Contributors: 淡江大學化學學系
    Keywords: Metallomesogens;Room temperature liquid crystals;Cobalt carboxylates;Cubic mesophase
    Date: 2015-01
    Issue Date: 2015-03-19 14:41:03 (UTC+8)
    Publisher: Oxford: Wiley-Blackwell Publishing Ltd.
    Abstract: Cobalt complexes of Co(3Cn)2(MeOH)4, derived from 3,4,5-trialkyloxybenzoate ligand (noted as 3Cn) with n = 10, 12, 14 and 16, were synthesized and characterized. The crystal of Co(1C12)2(MeOH)4 were determined by means of x-ray single crystal analysis. It crystallizes in the monoclinic P21/c space group with a = 24.3271(19) Å, b = 14.0058(11) Å, c = 6.4612(4) Å, α = γ = 90o, β = 94.368(4)o, and Z = 2. The phase texture and mesogenic properties were detected by polarized optical microscopic and powder x-ray diffraction technique. It was found that these compounds display the cubic phases. Differential scanning calorimetric data indicated that these compounds were nearly room temperature liquid crystalline and with a very wide mesogenic phase range.
    Relation: Journal of the Chinese Chemical Society 62(1), pp.26-32
    DOI: 10.1002/jccs.201400214
    Appears in Collections:[化學學系暨研究所] 期刊論文

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