An unprecedented 3D framework, [Ag(Ag6(C2-Me-(Mepdz)2)3(CH3CN))2](ClO4)13, has been synthesized by using a ligand with both rigid pyridazine and flexible hydrazone segments, which represents to the best of our knowledge, the first example of metallosupramolecule built by the triple-stranded helixes sharing the same penta-silver core.
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Journal of the Chinese Chemical Society 61(12), pp.1277-1280