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    Title: Synthesis of Polysubstituted Phenanthridines via Ligand-Free Copper-Catalyzed Annulation
    Authors: 陳彥甫;謝仁傑
    Contributors: 淡江大學化學學系
    Date: 2014
    Issue Date: 2015-01-28 11:05:12 (UTC+8)
    Publisher: Washington, DC: American Chemical Society
    Abstract: A novel procedure for the cascade reaction of the addition of a Grignard reagent to a nitrile with a copper-catalyzed C–N bond coupling was developed, which afforded various polysubstituted phenanthridines in moderate to good yields with tolerance for a wide variety of substrates. Experimental data demonstrated that the reaction proceeded more likely through a Cu(I/III) catalytic cycle.
    Relation: Organic Letters, 2014, 16(17), pp.4642-4645
    DOI: 10.1021/ol502237a
    Appears in Collections:[化學學系暨研究所] 期刊論文

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